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Synthesis, Structure, and Reactivity of an Imido‐ and an Oxo(imido)phosphorane RP(X)NR (XNH, O; R = t Bu 3 C 6 H 2
Author(s) -
Larbig Martin,
Nieger Martin,
von der Gönna Volker,
Ruban Alexander V.,
Niecke Edgar
Publication year - 1995
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199504601
Subject(s) - phosphorane , chemistry , reactivity (psychology) , derivative (finance) , stereochemistry , crystallography , medicinal chemistry , trigonal crystal system , oxygen atom , molecule , crystal structure , organic chemistry , medicine , alternative medicine , pathology , financial economics , economics
A high synthetic potential is promised by imido(imino)phosphorane 2 accessible by N 2 elimination from the azidophosphane 1 . In 2 , as in the isoelectronic oxygen derivative 3 , the phosphorus atom is in a trigonal‐planar environment. Ar = 2,4,6‐ t Bu 3 C 6 H 2 .