Synthesis, Structure, and Reactivity of an Imido‐ and an Oxo(imido)phosphorane RP(X)NR (XNH, O; R =  t Bu 3 C 6 H 2 | Zendy

Larbig Martin | Zendy; Nieger Martin | Zendy; von der Gönna Volker | Zendy; Ruban Alexander V. | Zendy; Niecke Edgar | Zendy

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Synthesis, Structure, and Reactivity of an Imido‐ and an Oxo(imido)phosphorane RP(X)NR (XNH, O; R = t Bu 3 C 6 H 2

Author(s) -

Larbig Martin,

Nieger Martin,

von der Gönna Volker,

Ruban Alexander V.,

Niecke Edgar

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199504601

Subject(s) - phosphorane , chemistry , reactivity (psychology) , derivative (finance) , stereochemistry , crystallography , medicinal chemistry , trigonal crystal system , oxygen atom , molecule , crystal structure , organic chemistry , medicine , alternative medicine , pathology , financial economics , economics

A high synthetic potential is promised by imido(imino)phosphorane 2 accessible by N 2 elimination from the azidophosphane 1 . In 2 , as in the isoelectronic oxygen derivative 3 , the phosphorus atom is in a trigonal‐planar environment. Ar = 2,4,6‐ t Bu 3 C 6 H 2 .

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