The Consequences of an Electrostatic “Forced Marriage” between Two Electron‐Rich Particles: Strained Ion Pairs | Zendy

Weiss Robert | Zendy; Brenner Thomas | Zendy; Hampel Frank | Zendy; Wolski Alexander | Zendy

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The Consequences of an Electrostatic “Forced Marriage” between Two Electron‐Rich Particles: Strained Ion Pairs

Author(s) -

Weiss Robert,

Brenner Thomas,

Hampel Frank,

Wolski Alexander

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199504391

Subject(s) - ion , hydrogen bond , chloride , electron , adduct , electron acceptor , chemistry , salt (chemistry) , tris , crystallography , inorganic chemistry , photochemistry , molecule , organic chemistry , physics , biochemistry , quantum mechanics

Because of the extraordinary electronic situation in tris(dimethylamino)cyclopropenylium chloride 1 , a salt with an electron‐rich cation and anion, the “naked” CI − ions in 1 show a very high readiness to coordinate to acceptors. Thus, stable adducts with hydrogen bonds are formed from 1 and carboxylic acids or phenol derivatives.

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