Surprising Formation of a Carborane‐Substituted Digallane | Zendy

Saxena Anil K. | Zendy; Zhang Hongming | Zendy; Maguire John A. | Zendy; Hosmane Narayan S. | Zendy; Cowley Alan H. | Zendy

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Surprising Formation of a Carborane‐Substituted Digallane

Author(s) -

Saxena Anil K.,

Zhang Hongming,

Maguire John A.,

Hosmane Narayan S.,

Cowley Alan H.

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199503321

Subject(s) - carborane , chemistry , polymer chemistry , atom (system on chip) , polar , medicinal chemistry , photochemistry , crystallography , organic chemistry , stereochemistry , materials science , physics , astronomy , computer science , embedded system

A very short GaGa bond , stabilized by carborane moieties, is present in the digallane 1 , which is air‐ and moisture‐sensitive, and soluble in both polar and nonpolar organic solvents. The coordination of each Ga atom to the respective C 2 B 3 carborane face is “slip distorted”. • = H, □ = SiMe 3 .

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