Compounds with Planar Tetracoordinate Boron Atoms: Anti van't Hoff/Le Bel Geometries without Metal Centers | Zendy

Menzel Matthias | Zendy; Steiner Dirk | Zendy; Winkler HeinzJürgen | Zendy; Schweikart Dieter | Zendy; Mehle Sigrid | Zendy; Fau Stefan | Zendy; Frenking Gernot | Zendy; Massa Werner | Zendy; Berndt Armin | Zendy

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Compounds with Planar Tetracoordinate Boron Atoms: Anti van't Hoff/Le Bel Geometries without Metal Centers

Author(s) -

Menzel Matthias,

Steiner Dirk,

Winkler HeinzJürgen,

Schweikart Dieter,

Mehle Sigrid,

Fau Stefan,

Frenking Gernot,

Massa Werner,

Berndt Armin

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199503271

Subject(s) - tetracoordinate , boron , planar , metal , crystallography , molecule , chemistry , materials science , organic chemistry , computer science , computer graphics (images)

Electropositive elements are prerequisites for the formation of anti van't Hoff/Le Bel geometries, as evident in compounds 1 , which contain planar tetracoordinate boron atoms in the CB 2 H framework. These compounds extend the range of molecules of this structural type to include those without metal atoms. R = CH(SiMe 3 ) 2 , R′ = 2,3,5,6‐Me 4 C 6 H.

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