[Fe(2,4,6‐ t Bu 3 C 6 H 2 ) 2 ], a Monomeric Diaryl Complex with Two‐Coordinate Iron( II ) | Zendy

Seidel Wolfgang | Zendy; Müller Hardy | Zendy; Görls Helmar | Zendy

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[Fe(2,4,6‐ t Bu 3 C 6 H 2 ) 2 ], a Monomeric Diaryl Complex with Two‐Coordinate Iron( II )

Author(s) -

Seidel Wolfgang,

Müller Hardy,

Görls Helmar

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199503251

Subject(s) - monomer , homoleptic , steric effects , chemistry , thermal stability , magnetic moment , center (category theory) , moment (physics) , crystallography , stereochemistry , physics , metal , condensed matter physics , organic chemistry , polymer , classical mechanics

The surprising thermal stability of the first monomeric, homoleptic diaryliron( II ) complex 1 arises because its Fe center is very well shielded by the sterically demanding ligands. The magnetic moment of 4.77 μ B indicates a high‐spin state of the highly soluble, air‐ and moisture‐sensitive complex.

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