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Does the Facile Inter‐ and Intramolecular CH Bond Activation by Tp * –Rh Complexes Proceed via Rh I or Rh III Intermediates?
Author(s) -
Pérez Pedro J.,
Poveda Manuel L.,
Carmona Ernesto
Publication year - 1995
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199502311
Subject(s) - intramolecular force , chemistry , benzene , medicinal chemistry , stereochemistry , rhodium , catalysis , organic chemistry
The answer to the question in the title may well be Rh 1 . Although initial studies suggested a mechanism involving a Rh III species of type 2 , the activation of the benzene CH group by 3 now appears to proceed via the intermediate 1 .
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