The Formation of a Mixed Organolithium Aggregate Li 4 R 2  n Bu 2  during the Heteroatom‐Assisted Lithiation of 1,3‐Bis(dimethylaminomethyl)‐2,4,6‐trimethylbenzene (R = 2,6‐(CH 2 NMe 2 ) 2 ‐3,5‐Me 2 C 6 HCH 2 ) | Zendy

Wijkens Peter | Zendy; van Koten Ernout M. | Zendy; Janssen Maurits D. | Zendy; Jastrzebski Johann T. B. H. | Zendy; Spek Anthony L. | Zendy; van Koten Gerard | Zendy

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The Formation of a Mixed Organolithium Aggregate Li 4 R 2 n Bu 2 during the Heteroatom‐Assisted Lithiation of 1,3‐Bis(dimethylaminomethyl)‐2,4,6‐trimethylbenzene (R = 2,6‐(CH 2 NMe 2 ) 2 ‐3,5‐Me 2 C 6 HCH 2 )

Author(s) -

Wijkens Peter,

van Koten Ernout M.,

Janssen Maurits D.,

Jastrzebski Johann T. B. H.,

Spek Anthony L.,

van Koten Gerard

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199502191

Subject(s) - heteroatom , butyllithium , chemistry , lithium (medication) , aggregate (composite) , medicinal chemistry , organic chemistry , materials science , ring (chemistry) , nanotechnology , medicine , endocrinology

Lithiated 1 and unreacted n ‐butyllithium in a 2:2 ratio make up the title aggregate 2 , which is formed in the reaction of 1 with two equivalents of n ‐butyllithium (shown below). Species such as 2 can be regarded as intermediates in heteroatom‐facilitated lithiation reactions.

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