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Trace Analysis of the Radionuclides 90 Sr and 89 Sr in Environmental Samples II: Accelerator Mass Spectrometry (AMS)
Author(s) -
Arslan Fatma,
Behrendt Martin,
Ernst Werner,
Finckh Eberhard,
Greb Gunther,
Gumbmann Friedrich,
Haller Martin,
Hofmann Stefan,
Karschnick Ralf,
Klein Matthias,
Kretschmer Wolfgang,
Mackiol Jochen,
Morgenroth Gerhard,
Pagels Christian,
Schleicher Markus
Publication year - 1995
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199501831
Subject(s) - nuclide , radiochemistry , plutonium , chemistry , mass spectrometry , accelerator mass spectrometry , strontium , fission products , uranium , strontium 90 , radionuclide , nuclear physics , chromatography , physics , organic chemistry
Strontium‐90 is one of the most poisonous radionuclides . Its toxicity results from its long half‐life of 28.5 years and permanent deposition in the blood‐forming bone system. Strontium‐90 is formed in high yields during the nuclear fission of uranium‐235 and plutonium‐239. The classic analytical procedure for the determination of 90 Sr, which relies on the β − ‐radiation of the daughter nuclide yttrium‐90, necessitates the chemical removal of all accompanying nuclides. This method requires the Sr/Y ratio to be at equilibrium which takes about two to three weeks to achieve—far too long for the analysis of acute contaminations. Three communications deal with new procedures for ultra‐trace analysis using complex physical detection methods (resonance ionization and accelerator mass spectrometry) and high‐performance separation techniques (high‐performance ion chromatography, HPIC) are presented. In accordance with the strategies of the German Federal Ministry of the Environment, Nature Conservation, and Nuclear Safety, precision methods are described for the determination of the strontium‐90 content in aerosols. These techniques yield data for calculations of the spread of contaminants, which in turn yield results that can be verified in various samples with the aid of the novel fast detection method (HPIC with on‐line detectors). The three analytical procedures are set up in a modular manner and can therefore be utilized in variable combinations. They also indicate the high level of refinement achieved by modern ultra‐trace analyses.