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Aggregation of Nitrido–Metal Complexes: The Example of [(η 5 ‐C 5 Me 5 )Mo(N)Cl 2 ]
Author(s) -
Herrmann Wolfgang A.,
Bogdanovic Sandra,
Priermeier Thomas,
Poli Rinaldo,
Fettinger James C.
Publication year - 1995
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199501121
Subject(s) - delocalized electron , nucleophile , metal , ligand (biochemistry) , chemistry , nitrogen , stereochemistry , crystallography , medicinal chemistry , polymer chemistry , organic chemistry , catalysis , biochemistry , receptor
The reactive nitridomolybdenum( VI ) fragment 1 is available from the reaction of [Cp 2 * Mo 2 Cl 6 ] with azides. Aggregation occurs in different ways depending on the conditions to afford compounds containing six‐membered rings with either localized or delocalized metal–nitrogen multiple bonds. The nature and structure of the products indicates that 1 has a nucleophilic nitrido ligand.