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Mononuclear Tris(arene)–Metal Complexes
Author(s) -
Zenneck Ulrich
Publication year - 1995
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199500531
Subject(s) - tris , halide , metal , chemistry , metal halides , salt (chemistry) , potassium , polymer chemistry , medicinal chemistry , stereochemistry , organic chemistry , biochemistry
The reaction of arene anions with metal halides is not only an elegant approach to arenemetalates, but may also lead to structurally novel complexes, as Ellis et al. recently found ( Angew. Chem. Int. Ed. Engl. 1994 , 33 , 1973–1975) in, for instance, the potassium salt of 1 , the first tris(arene)metal complex with three independent arene ligands.