Alternating Ferro‐ and Antiferromagnetic Interactions in a Mn II  Chain with Alternating End‐On and End‐to‐End Bridging Azido Ligands | Zendy

Cortés Roberto | Zendy; Lezama Luis | Zendy; Rojo Teófilo | Zendy; Arriortua M. Isabel | Zendy; Pizarro J. Luis | Zendy; Solans Xavier | Zendy

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Alternating Ferro‐ and Antiferromagnetic Interactions in a Mn II Chain with Alternating End‐On and End‐to‐End Bridging Azido Ligands

Author(s) -

Cortés Roberto,

Lezama Luis,

Rojo Teófilo,

Arriortua M. Isabel,

Pizarro J. Luis,

Solans Xavier

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199424881

Subject(s) - antiferromagnetism , crystallography , chemistry , copper , ion , crystal structure , bridging (networking) , stereochemistry , physics , condensed matter physics , organic chemistry , computer network , computer science

Mn(ClO 4 ) 2 ·6H 2 O, 2,2'‐bipyridine, and NaN 3 were used to synthesize [Mn(N 3 ) 2 ‐(bpy)] χ , the crystal structure of which (shown below) is characterized by alternating end‐on and end‐to‐end bridging azido ligands. The existence of alternating ferro‐and antiferromagnetic interactions between the S = 5/2 ions, as found previously only in copper(II) complexes, is suggested.

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