A Regioselective Palladium‐Catalyzed Reduction of 3,3‐Heterobimetalated Allylic Acetates— Synthesis and Reactivity of Allylic Bimetallic Compounds | Zendy

Lautens Mark | Zendy; Delanghe Patrick H. M. | Zendy

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A Regioselective Palladium‐Catalyzed Reduction of 3,3‐Heterobimetalated Allylic Acetates— Synthesis and Reactivity of Allylic Bimetallic Compounds

Author(s) -

Lautens Mark,

Delanghe Patrick H. M.

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199424481

Subject(s) - allylic rearrangement , regioselectivity , chemistry , bimetallic strip , palladium , reagent , catalysis , hydride , reactivity (psychology) , organic chemistry , hydrosilylation , medicinal chemistry , combinatorial chemistry , hydrogen , medicine , alternative medicine , pathology

Selective reaction of one of two CSi bonds in 1 with octanal yields 2 . The disilyl compound 1 and also silylstannyl compounds, useful reagents in organic synthesis, could be prepared regioselectively (>99:1) by hydride reduction of allylic acetates.

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