Platinum–Iron Silylene Complexes and Metal‐Promoted Substituent Exchange between Si(NMe 2 ) 3  and P(OEt) 3  Ligands | Zendy

Bodensieck Ulf | Zendy; Braunstein Pierre | Zendy; Faure Thierry | Zendy; Knorr Michael | Zendy; Stern Christine | Zendy; Deck Werner | Zendy

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Platinum–Iron Silylene Complexes and Metal‐Promoted Substituent Exchange between Si(NMe 2 ) 3 and P(OEt) 3 Ligands

Author(s) -

Bodensieck Ulf,

Braunstein Pierre,

Faure Thierry,

Knorr Michael,

Stern Christine,

Deck Werner

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199424401

Subject(s) - silylene , chemistry , substituent , metal , ligand (biochemistry) , medicinal chemistry , main group element , stereochemistry , transition metal , silicon , catalysis , organic chemistry , receptor , biochemistry

The silylene complexes 1 are stabilized by the electron‐deficient metal fragment PtL 2 rather than by a more usual electron‐donating group. The base‐stabilized silylene complex 2 is formed in the reaction of [Fe(CO) 4 {P(OEt) 3 }] with HSi(NMe 2 ) 3 as a result of an unprecedented exchange of OEt and NMe 2 ligand substituents.

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