Excited‐State Carbon Acids: Theoretical Studies of Suberene and Cycloheptatriene | Zendy

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Excited‐State Carbon Acids: Theoretical Studies of Suberene and Cycloheptatriene

Author(s) -

Steuhl HansMartin,

Klessinger Martin

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199424311

Subject(s) - cycloheptatriene , excited state , deprotonation , ring (chemistry) , derivative (finance) , closure (psychology) , trace (psycholinguistics) , relaxation (psychology) , chemistry , state (computer science) , carbon fibers , atomic physics , computational chemistry , photochemistry , physics , mathematics , organic chemistry , financial economics , economics , market economy , ion , social psychology , psychology , composite number , linguistics , philosophy , algorithm

Hydrogen shift and ring closure instead of deprotonation: Cycloheptatriene ( 2 ) does not show the photoreactivity expected from MO considerations, in contrast with the dibenzo derivative 1 . Semiempirical calculations trace this difference to the crossing of states on relaxation of the excited state of 2 .

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