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Porphyrin–Quinone Cyclophanes with Gradually Varied Donor–Acceptor Distances
Author(s) -
Staab Heinz A.,
Hauck Ralf,
Feurer Achim
Publication year - 1995
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199424281
Subject(s) - quinone , anthracene , porphyrin , cyclophane , chemistry , naphthalene , acceptor , photochemistry , electron transfer , benzene , crystallography , electron acceptor , stereochemistry , crystal structure , organic chemistry , physics , condensed matter physics
How does the rate of electron transfer between the quinone and porphyrin units in cyclophanes of type 1 vary with distance? H. A. Staab et al. report here on the synthesis and properties of cyclophanes with benzene, naphthalene ( 1 ), and anthracene spacers, which were examined by spectroscopy, X‐ray structure analysis, and molecular dynamics calculations.