Synthesis of the First Microporous Aluminum Phosphonate with Organic Groups Covalently Bonded to the Skeleton | Zendy

Maeda Kazuyuki | Zendy; Kiyozumi Yoshimichi | Zendy; Mizukami Fujio | Zendy

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Synthesis of the First Microporous Aluminum Phosphonate with Organic Groups Covalently Bonded to the Skeleton

Author(s) -

Maeda Kazuyuki,

Kiyozumi Yoshimichi,

Mizukami Fujio

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199423351

Subject(s) - microporous material , phosphonate , molecular sieve , covalent bond , hydrothermal synthesis , crystallography , hydrothermal circulation , group (periodic table) , chemistry , materials science , stereochemistry , chemical engineering , organic chemistry , adsorption , engineering

A hydrothermal procedure is used to prepare the molecular sieve Al 2 (CH 3 PO 3 )3 ( 1 ). This compound has a new three‐dimensional framework, in which one six‐coordinate and two four‐coordinate Al centers are bound to the CH 3 PO 3 units. The channel walls of the micropores of 1 are probably not lined with O atoms but with methyl groups.

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