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Synthesis of the First Microporous Aluminum Phosphonate with Organic Groups Covalently Bonded to the Skeleton
Author(s) -
Maeda Kazuyuki,
Kiyozumi Yoshimichi,
Mizukami Fujio
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199423351
Subject(s) - microporous material , phosphonate , molecular sieve , covalent bond , hydrothermal synthesis , crystallography , hydrothermal circulation , group (periodic table) , chemistry , materials science , stereochemistry , chemical engineering , organic chemistry , adsorption , engineering
A hydrothermal procedure is used to prepare the molecular sieve Al 2 (CH 3 PO 3 )3 ( 1 ). This compound has a new three‐dimensional framework, in which one six‐coordinate and two four‐coordinate Al centers are bound to the CH 3 PO 3 units. The channel walls of the micropores of 1 are probably not lined with O atoms but with methyl groups.