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Synthesis and Structure of the First Stable Germaneselone
Author(s) -
Matsumoto Tsuyoshi,
Tokitoh Norihiro,
Okazaki Renji
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199423161
Subject(s) - monomer , atmosphere (unit) , aryl , inert gas , inert , moisture , materials science , polymer chemistry , chemistry , chemical engineering , polymer , organic chemistry , composite material , meteorology , physics , engineering , alkyl
Air‐ and moisture‐sensitive , yet thermally stable under an inert atmosphere, the diaryl germaneselone 2 is synthesized by deselenation of heterocycle 1 . The aryl substituents shield the GeSe bond and thus hinder oligomerization of the monomer 2 .