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A 1,3‐Diboratabenzene
Author(s) -
Balzereit Christian,
Winkler HeinzJürgen,
Massa Werner,
Berndt Armin
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199423061
Subject(s) - dilithium , lithium (medication) , ring (chemistry) , ion , planar , reduction (mathematics) , crystallography , materials science , chemistry , stereochemistry , mathematics , psychology , geometry , computer science , organic chemistry , psychiatry , computer graphics (images) , deprotonation
The first dilithium compound of a 1,3‐diboratabenzene ( 1 shown on the right) was synthesized by reduction (Li/THF) of a tetracarbahexaborane. Its lithium ions are positioned 170.3 pm above and 166.6 pm below the nearly planar six‐membered ring.