Premium
Nonclassical 1,2‐Diboretanes and 1,2‐Diborolanes
Author(s) -
Steiner Dirk,
Balzereit Christian,
Winkler HeinzJürgen,
Stamatis Nicolaos,
Massa Werner,
Berndt Armin,
Hofmann Matthias,
von Ragué Schleyer Paul
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199423031
Subject(s) - boron , ring (chemistry) , chemistry , crystallography , bridge (graph theory) , stereochemistry , organic chemistry , medicine
Experiment and theory both indicate that four‐ and five‐membered rings containing two neighboring boron atoms–like the corresponding three‐membered ring compounds—favor nonclassical structures with a B‐H‐B bridge ( 1 and 2 , respectively) when the electron deficiency at boron is not reduced by donor substituents.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom