Phosphane Coordination to Magnesium: Synthesis and Structure of Bis[ ortho, ortho′ ‐bis{(dimethylphosphino)‐methyl}phenyl]magnesium | Zendy

Pape Andreas | Zendy; Lutz Martin | Zendy; Müller Gerhard | Zendy

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Phosphane Coordination to Magnesium: Synthesis and Structure of Bis[ ortho, ortho′ ‐bis{(dimethylphosphino)‐methyl}phenyl]magnesium

Author(s) -

Pape Andreas,

Lutz Martin,

Müller Gerhard

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199422811

Subject(s) - magnesium , octahedron , chemistry , reagent , chelation , octahedral molecular geometry , atom (system on chip) , coordination geometry , crystal structure , stereochemistry , medicinal chemistry , crystallography , inorganic chemistry , molecule , organic chemistry , hydrogen bond , computer science , embedded system

The formation of four structurally favorable five‐membered chelate rings stabilizes the first isolated organomagnesium phosphane complex 2 . This complex is obtained by the addition of MgCl 2 to the new organolithium reagent 1 . The structure of 2 , in which the Mg atom is six‐coordinate with a distorted octahedral coordination geometry, is maintained in solution.

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