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Dimesityldioxirane—A Dioxirane Stable in the Solid State
Author(s) -
Kirschfeld Andreas,
Muthusamy Sengodagounder,
Sander Wolfram
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199422121
Subject(s) - dioxirane , diazomethane , solid state , oxide , materials science , chemistry , chemical engineering , organic chemistry , engineering
On a preparative scale of 10 mg per batch the dioxirane 2 can be synthesized from the diazomethane 1 . Compound 2 is the first dioxirane that is stable in the solid state at room temperature. An intermediate, probably the carbonyl oxide, can also be kept for several hours in solution at –78°C.
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