Premium
A Novel Hexamer of Bu t C P: Synthesis, Structure, and Theoretical Studies
Author(s) -
Caliman Vinicius,
Hitchcock Peter B.,
Nixon John F.,
Hofmann Matthias,
von Rague Schleyer Paul
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199422021
Subject(s) - random hexamer , chemistry , stereochemistry , computational chemistry , crystallography , mathematics
Constructed from six phosphaalkyne units , the organophosphorus compound P 6 C 6 t Bu 6 ( 1 ) can be considered to have a structure derived from the corresponding tetraphosphacubane in which two opposite carbon corners have been replaced by CCP rings. The hexamer 1 therefore has the same structure as the D 3d symmetric (CH) 12 hydrocarbon p ‐[3 2 .5 6 ]octahedrane and the hypothetical P 12 .
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom