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Monomeric Tris(imino)metaphosphates
Author(s) -
Niecke Edgar,
Frost Matthias,
Nieger Martin,
von der Gönna Volker,
Ruban Alexander,
Schoeller Wolfgang W.
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199421111
Subject(s) - monomer , tris , chemistry , solvent , nitrogen , ion , polymer chemistry , crystallography , polymer , organic chemistry , biochemistry
Nitrogen analogues of monomeric PO 3 −can be obtained as Li + salts. Depending on the substituents at the nitrogen atoms, the anion is either coordinated to Li as in 1 or separated from the cation as in 2 . The anion in 2 has a propellerlike structure. Ar = 2,4,6‐tri‐ tert ‐butyrphenyl, D = donor solvent.