Polynuclear Lanthanide Complexes: Formation of a Selenium‐Centered Sm 6  Complex, [{(C 5 Me 5 )Sm} 6 Se 11 ] | Zendy

Evans William J. | Zendy; Rabe Gerd W. | Zendy; Ansari Mohammad A. | Zendy; Ziller Joseph W. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Polynuclear Lanthanide Complexes: Formation of a Selenium‐Centered Sm 6 Complex, [{(C 5 Me 5 )Sm} 6 Se 11 ]

Author(s) -

Evans William J.,

Rabe Gerd W.,

Ansari Mohammad A.,

Ziller Joseph W.

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199421101

Subject(s) - selenium , lanthanide , octahedron , moiety , atom (system on chip) , chemistry , crystallography , ion , stereochemistry , crystal structure , organic chemistry , computer science , embedded system

The central Se atom is surrounded by six (C 5 Me 5 )Sm units in a distorted octahedral arrangement in the title compounds (structure shown on the right). Four pairs of (Se 2 ) 2− units, the central Se atom, and two further Se atoms connect the six (C 5 Me 5 )Sm units. The complex contains a linear (Se 3 ) 4− moiety, which is isoelectronic with the (I 3 ) ion.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research