Synthesis, Structure, and Thermolysis of a Tetracoordinate 1,2λ 4 ‐Oxathietane | Zendy

Kawashima Takayuki | Zendy; Ohno Fumihiko | Zendy; Okazaki Renji | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Synthesis, Structure, and Thermolysis of a Tetracoordinate 1,2λ 4 ‐Oxathietane

Author(s) -

Kawashima Takayuki,

Ohno Fumihiko,

Okazaki Renji

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199420941

Subject(s) - tetracoordinate , thermal decomposition , benzophenone , decomposition , chemistry , ketone , medicinal chemistry , olefin fiber , organic chemistry , catalysis , computer graphics (images) , computer science , planar

Oxidative cyclization of 1 with Br 2 yields the tetracoordinate 1,2λ 4 ‐oxathietane 2 . Instead of an olefin, thermolysis of 2 provided benzophenone and the ketone formed by migration of a phenyl group. Traces of 2,2,3‐triphenyloxirane were observed, which hints that a 1,2λ 4 ‐oxathietane may be an intermediate in the Corey–Chaykovsky reaction.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research