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Cyanide–Isocyanide Isomerism in CN‐Bridged Organometallic Complexes
Author(s) -
Zhu Nianyong,
Vahrenkamp Heinrich
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199420901
Subject(s) - prussian blue , isocyanide , cyanide , chemistry , organometallic chemistry , group 2 organometallic chemistry , polymer chemistry , stereochemistry , medicinal chemistry , crystallography , organic chemistry , molecule , crystal structure , electrochemistry , electrode
The inertness of the organometallic building blocks makes it surprisingly easy to prepare the two isomeric forms of CN‐bridged heterodinuclear complexes like 1 a and 1 b . Compounds like these should contribute to the understanding of “molecular Prussian Blue”, dppe = 1,2‐bis(diphenylphosphano)ethane.\documentclass{article}\usepackage{amssymb}\pagestyle{empty}\begin{document}$$[{\rm (CO)}_5{\rm Cr}(\mu\hbox{-CN}){\rm Fe(dppe)Cp}]\quad{\bf 1a}\qquad[{\rm (CO)}_5{\rm Cr}(\mu\hbox{-NC}){\rm Fe(dppe)Cp}]\quad{\bf 1b}$$\end{document}