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[Cp 2 Ti(CC t Bu) 2 ] as an Alkynyl Transfer Reagent: Synthesis and Characterization of the Asymmetrically Bridged Heterodimetallic Complex [Cp 2 Ti(CC t Bu) 2 Pt(PPh 3 )]·0.5 THF
Author(s) -
Berenguer Jesús R.,
Forniés Juan,
Lalinde Elena,
Martín Antonio
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199420831
Subject(s) - cyclopentadienyl complex , reagent , chemistry , solid state , characterization (materials science) , stereochemistry , metal , crystallography , materials science , nanotechnology , catalysis , organic chemistry
The coordination in A and B are not the only modes possible when dialkynylbis(cyclopentadienyl)titanium complexes coordinate other metal complex fragments. The reaction of [Cp 2 Ti(CC t Bu) 2 ] with [Pt(C 2 H 4 )(PPh 3 ) 2 ] affords a dinuclear complex which has structure C in the solid state. Dynamic processes are evident for this complex in solution.