[Cp 2 Ti(CC t Bu) 2 ] as an Alkynyl Transfer Reagent: Synthesis and Characterization of the Asymmetrically Bridged Heterodimetallic Complex [Cp 2 Ti(CC t Bu) 2 Pt(PPh 3 )]·0.5 THF | Zendy

Berenguer Jesús R. | Zendy; Forniés Juan | Zendy; Lalinde Elena | Zendy; Martín Antonio | Zendy

Premium

[Cp 2 Ti(CC t Bu) 2 ] as an Alkynyl Transfer Reagent: Synthesis and Characterization of the Asymmetrically Bridged Heterodimetallic Complex [Cp 2 Ti(CC t Bu) 2 Pt(PPh 3 )]·0.5 THF

Author(s) -

Berenguer Jesús R.,

Forniés Juan,

Lalinde Elena,

Martín Antonio

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199420831

Subject(s) - cyclopentadienyl complex , reagent , chemistry , solid state , characterization (materials science) , stereochemistry , metal , crystallography , materials science , nanotechnology , catalysis , organic chemistry

The coordination in A and B are not the only modes possible when dialkynylbis(cyclopentadienyl)titanium complexes coordinate other metal complex fragments. The reaction of [Cp 2 Ti(CC t Bu) 2 ] with [Pt(C 2 H 4 )(PPh 3 ) 2 ] affords a dinuclear complex which has structure C in the solid state. Dynamic processes are evident for this complex in solution.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research