Totally Enantioselective Inversion of Configuration of ( S )‐(+)‐Carnitine Derivatives | Zendy

Bernabei Ida | Zendy; Castagnani Roberto | Zendy; De Angelis Francesco | Zendy; De Witt Scalfaro Paolo | Zendy; Giannessi Fabio | Zendy; Misiti Domenico | Zendy; Muck Sandra | Zendy; Scafetta Nazareno | Zendy; Tinti Maria Ornella | Zendy

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Totally Enantioselective Inversion of Configuration of ( S )‐(+)‐Carnitine Derivatives

Author(s) -

Bernabei Ida,

Castagnani Roberto,

De Angelis Francesco,

De Witt Scalfaro Paolo,

Giannessi Fabio,

Misiti Domenico,

Muck Sandra,

Scafetta Nazareno,

Tinti Maria Ornella

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199420761

Subject(s) - enantioselective synthesis , yield (engineering) , carnitine , inversion (geology) , combinatorial chemistry , chemistry , stereochemistry , lactone , sequence (biology) , mathematics , organic chemistry , materials science , catalysis , biology , biochemistry , paleontology , structural basin , metallurgy

Tons of waste ( S )‐carnitinamide 1 are obtained in the industrial production of the ( R ) isomer 3 , which is a biologically active pharmaceutical product. A method has now been developed to recycle 1 in a five‐step reaction sequence with 80% overall yield via β‐lactone 2 .

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