The First Structurally Characterized Metal Complex Involving the Free Acid of a New Tris(pyrazolyl)borate as Ligand | Zendy

Rheingold Arnold L. | Zendy; Haggerty Brian S. | Zendy; Trofimenko Swiatoslaw | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

The First Structurally Characterized Metal Complex Involving the Free Acid of a New Tris(pyrazolyl)borate as Ligand

Author(s) -

Rheingold Arnold L.,

Haggerty Brian S.,

Trofimenko Swiatoslaw

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199419831

Subject(s) - protonation , chemistry , boron , ligand (biochemistry) , tris , metal , hydrogen bond , medicinal chemistry , tripodal ligand , stereochemistry , crystallography , molecule , organic chemistry , receptor , ion , biochemistry

One of the three pyrazolyl groups of the scorpionato ligand occurs in the protonated form in the bright orange Cu complex [(Tp Cy )HCuCl 2 ] ( 1 ) and forms a hydrogen bond with a Cu‐bound Cl atom. In the reaction of [Tp Cy Tl] with CuCl 2 ṁ2H 2 O. 1 is formed rather than the expected complex [Tp Cy MCl] (Tp Cy = [HB(cyclohexylpyrazolyl) 3 ], R = Cy = cyclohexyl).

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research