Benzobis(thiadiazole)s Containing Hypervalent Sulfur Atoms: Novel Heterocycles with High Electron Affinity and Short Intermolecular Contacts between Heteroatoms | Zendy

Ono Katsuhiko | Zendy; Tanaka Shoji | Zendy; Yamashita Yoshiro | Zendy

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Benzobis(thiadiazole)s Containing Hypervalent Sulfur Atoms: Novel Heterocycles with High Electron Affinity and Short Intermolecular Contacts between Heteroatoms

Author(s) -

Ono Katsuhiko,

Tanaka Shoji,

Yamashita Yoshiro

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199419771

Subject(s) - hypervalent molecule , heteroatom , intermolecular force , chemistry , sulfur , crystallography , electron affinity (data page) , ribbon , stereochemistry , electron , crystal structure , materials science , molecule , organic chemistry , ring (chemistry) , physics , reagent , composite material , quantum mechanics

Ribbon‐type columns linked to form a network are found in the crystal structure of 1 , R = Br. This compound differs significantly from the Kekulé‐type analogue 2 in terms of its electron affinity and the position of its UV/VIS absorption maximum. The monoselenium analogues of 1 were also synthesized and characterized.

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