2,2′‐Bipyrenyl and  para ‐Terpyrenyl—A New Type of Electronically Decoupled Oligoarylene | Zendy

Kreyenschmidt Martin | Zendy; Baumgarten Martin | Zendy; Tyutyulkov Nikolay | Zendy; Müllen Klaus | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

2,2′‐Bipyrenyl and para ‐Terpyrenyl—A New Type of Electronically Decoupled Oligoarylene

Author(s) -

Kreyenschmidt Martin,

Baumgarten Martin,

Tyutyulkov Nikolay,

Müllen Klaus

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199419571

Subject(s) - bridging (networking) , decoupling (probability) , atomic orbital , biphenyl , pyrene , phenylene , chemistry , materials science , crystallography , physics , computer science , organic chemistry , engineering , quantum mechanics , electron , computer network , control engineering , polymer

By bridging over centers that lie in nodal planes of the frontier orbitals , the electronic decoupling of the pyrene units in the new compounds bipyrenyl 1 and para ‐terpyrenyl 2 is achieved. This causes the electronic situation to differ fundamentally from that in biphenyl, oligo( para ‐phenylene)s, and related oligoarylenes. R is, for example, n ‐pentyl.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research