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Cover Picture (Angew. Chem. Int. Ed. Engl. 19/1994)
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199418951
Subject(s) - cover (algebra) , chemistry , ligand (biochemistry) , crystallography , stereochemistry , computer science , library science , engineering , mechanical engineering , biochemistry , receptor
The cover picture shows a ball‐and‐stick model of the first peroxocopper( II ) complex [(Cu 4 L 2 )(O 2 )(OMe) 2 (ClO 4 )] + (L = anion of the tridentate ligand 4‐methyl‐2,6‐bis‐(pyrrolidinomethyl)phenol) stable at room temperature. This cation (color code: Cu brown, O red, N blue, C black, Cl green) is characterized by several unusual structural details, including a μ 4 ‐bridging O 2 ligand and a ClO 4 ligand bound unsymmetrically to the Cu 4 center. The picture was produced with the program POV‐Ray on a IBM Workstation by Dipl.‐Chem. S. J. Schindler, Further information on the structural and spectroscopic properties of this compound, which are of general interest for biochemistry and coordination chemistry, are reported by B. Krebs and J. Reimm on pages 1969ff.