A Postulated Carrier of Gold in Hydrothermal Ore Solutions: Synthesis and Crystal Structure of [(Ph 3 P) 2 N][Au(SH) 2 ], the First Homoleptic Hydrogensulfido Complex | Zendy

Vicente José | Zendy; Chicote MaríaTeresa | Zendy; GonzálezHerrero Pablo | Zendy; Jones Peter G. | Zendy; Ahrens Birte | Zendy

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A Postulated Carrier of Gold in Hydrothermal Ore Solutions: Synthesis and Crystal Structure of [(Ph 3 P) 2 N][Au(SH) 2 ], the First Homoleptic Hydrogensulfido Complex

Author(s) -

Vicente José,

Chicote MaríaTeresa,

GonzálezHerrero Pablo,

Jones Peter G.,

Ahrens Birte

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199418521

Subject(s) - homoleptic , organosulfur compounds , chemistry , hydrogen sulfide , counterion , sulfide , inorganic chemistry , hydrothermal circulation , catalysis , sulfur , organic chemistry , ion , chemical engineering , metal , engineering

Not an insoluble sulfide , but the homoleptic gold complex 1 , which is stable without any auxiliary ligands, is formed in the reaction of bis(acetylacetonato)gold( I ) with hydrogen sulfide [Eq. (a)]. Complexes of this type are of interest as intermediates in the catalytic hydrodesulfuration of organosulfur compounds. Counterion: [(Ph 3 P) 2 N] + .

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