Oxygen Evolution by Oxidation of Water with Manganese Porphyrin Dimers | Zendy

Naruta Yoshinori | Zendy; Sasayama Masaaki | Zendy; Sasaki Takao | Zendy

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Oxygen Evolution by Oxidation of Water with Manganese Porphyrin Dimers

Author(s) -

Naruta Yoshinori,

Sasayama Masaaki,

Sasaki Takao

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199418391

Subject(s) - manganese , photosystem ii , oxygen evolution , chemistry , oxygen evolving complex , aqueous solution , acetonitrile , oxygen , porphyrin , photochemistry , inorganic chemistry , counterion , photosynthesis , electrochemistry , ion , organic chemistry , biochemistry , electrode

A functional model for the tetranuclear manganese cluster in the photosystem II of higher plants and cyanobacteria is now provided by binuclear dicationic manganese complexes such as 1 . In the anodic oxidation of aqueous acetonitrile containing these complexes water is oxidized to oxygen by a four‐electron process. An example of Ar is 4‐ t BuC 6 H 4 ; counterion ClO 4 − .

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