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Subvalent Aluminum Halides as Examples of High‐Temperature Species in Inorganic Syntheses
Author(s) -
Schneider Jörg J.
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199418301
Subject(s) - halide , aluminium , yield (engineering) , reagent , chemistry , inorganic chemistry , materials science , organic chemistry , metallurgy
Chemistry under extreme conditions makes the synthesis of 1 and 2 possible. AlBr is formed by cocondensation of Al atoms and HBr and trapped with different reagents and at different temperatures to yield the first donor‐stabilized aluminum( I ) and aluminum( II ) halides isolable at room temperature.