Two‐Dimensional Sheets of Tetragonal Copper( II ) Lattices: X‐Ray Crystal Structure and Magnetic Properties of [Cu(C 6 O 4 Cl 2 )(C 4 H 4 N 2 )]  n | Zendy

Kawata Satoshi | Zendy; Kitagawa Susumu | Zendy; Kondo Mitsuru | Zendy; Furuchi Isamu | Zendy; Munakata Megumu | Zendy

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Two‐Dimensional Sheets of Tetragonal Copper( II ) Lattices: X‐Ray Crystal Structure and Magnetic Properties of [Cu(C 6 O 4 Cl 2 )(C 4 H 4 N 2 )] n

Author(s) -

Kawata Satoshi,

Kitagawa Susumu,

Kondo Mitsuru,

Furuchi Isamu,

Munakata Megumu

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199417591

Subject(s) - tetragonal crystal system , antiferromagnetism , copper , crystallography , hydrogen bond , crystal structure , singlet state , ground state , chemistry , pyrazine , materials science , condensed matter physics , physics , stereochemistry , molecule , atomic physics , excited state , organic chemistry

Cu II chains linked by chloranilate dianions function as the warp and pyrazine ligands as the woof in a “woven” two‐dimensional coordination polymer. A section of the title compound is shown below. This arrangment leads to weak antiferromagnetic interactions between the metal centers and a singlet ground state. An analogous coordination polymer can be constructed with methanol as a hydrogen‐bond donor.

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