Thianickelacycles by Ring‐Opening Reactions of Cyclic Thioethers and Their Subsequent Carbonylation to Thioesters | Zendy

Matsunaga Phillip T. | Zendy; Hillhouse Gregory L. | Zendy

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Thianickelacycles by Ring‐Opening Reactions of Cyclic Thioethers and Their Subsequent Carbonylation to Thioesters

Author(s) -

Matsunaga Phillip T.,

Hillhouse Gregory L.

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199417481

Subject(s) - chemistry , carbonylation , yield (engineering) , sulfide , ethylene , nickel , ring (chemistry) , medicinal chemistry , oxidative addition , organic chemistry , photochemistry , carbon monoxide , catalysis , materials science , metallurgy

A functional model for the nickel‐containing CO‐dehydrogenase? Oxidative addition reactions of ethylene sulfide, propylene sulfide, and thietane with nickel complexes like 1 yield thianickelacycles. Formally analogous to the biosynthesis of acetyl coenzyme A, 2 undergoes an insertion reaction with CO followed by reductive elimination of the thiobutyrolactone 3 .

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