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Linear Coordination Polymers of Copper( II ) and Fourfold Deprotonated Sugar Alcohols
Author(s) -
Klüfers Peter,
Schuhmacher Jörg
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199417421
Subject(s) - deprotonation , intramolecular force , chemistry , hydrogen bond , copper , erythritol , polymer chemistry , stereochemistry , organic chemistry , molecule , ion , biochemistry
Complex structures with polyols as ligands : The respective tetra‐ and hexaalcohols erythritol and dulcitol undergo fourfold deprotonation in the presence of Cu II to form linear, anionic coordination polymers. In addition, dulcitol forms intramolecular hydrogen bonds (see right).