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Three‐Dimensional Interpenetrating Double and Triple Framework Structures in [Cd(bpy) 2 {Ag(CN) 2 } 2 ] and [Cd(pyrz){Ag 2 (CN) 3 }{Ag(CN) 2 }]
Author(s) -
Soma Takayoshi,
Yuge Hidetaka,
Iwamoto Toschitake
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199416651
Subject(s) - pyrazine , crystallography , chemistry , materials science , stereochemistry
No bonding interactions exist between the three interpenetrating framework structures in 1 , and all of the two‐dimensional networks are constructed by coordinate linkages‐these two principles describe the structure of 1 (shown schematically on the right). Compound 1 was prepared from K 2 [Cd(CN) 4 ], Ag‐NO 3 , and pyrazine at pH 10.
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