Preparation and Structure of C 76 (S 8 ) 6 : A First Step in the Crystallographic Investigation of Higher Fullerenes | Zendy

Michel Rudi H. | Zendy; Kappes Manfred M. | Zendy; Adelmann Peter | Zendy; Roth Georg | Zendy

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Preparation and Structure of C 76 (S 8 ) 6 : A First Step in the Crystallographic Investigation of Higher Fullerenes

Author(s) -

Michel Rudi H.,

Kappes Manfred M.,

Adelmann Peter,

Roth Georg

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199416511

Subject(s) - fullerene , crystallography , molecule , crystal structure , diffraction , adduct , x ray crystallography , sulfur , materials science , symmetry (geometry) , chemistry , optics , physics , organic chemistry , geometry , mathematics , metallurgy

A sandwich‐like structure , in which planes of closely packed C 76 molecules are interleaved with layers of S 8 rings, is formed by the fullerene‐sulfur adduct. C 76 (S 8 ) 6 (shown on the right). The structure of this compound has been studied by single‐crystal X‐ray diffraction. The results are consistent with a chiral C 76 molecule with D 2 symmetry.

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