Premium
The Use of Heterometallic Bridging Moieties To Generate Tractable Lanthanide Complexes of Small Ligands
Author(s) -
Evans William J.,
Anwander Reiner,
Doedens Robert J.,
Ziller Joseph W.
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199416411
Subject(s) - lanthanide , amide , bridging (networking) , chemistry , neodymium , hexane , combinatorial chemistry , polymer chemistry , stereochemistry , organic chemistry , computer science , ion , computer network , laser , physics , optics
Hexane‐soluble derivatives of neodymium amide Nd‐(NMe 2 ) 3 such as 1 or the unsolvated heterometallic peralkyl compound 2 form in the reaction of MMe 3 (M = Al, Ga) with 3 . This provides a route to soluble lanthanide complexes with small ligands.