Octahydro‐1,2,3:4,5,6‐dimethenopentalene‐2‐carbonitrile, the First Derivative of a Yet‐Unknown (CH) 10  Hydrocarbon | Zendy

Christl Manfred | Zendy; Türk Michael | Zendy; Peters EvaMaria | Zendy; Peters Karl | Zendy; von Schnering Hans Georg | Zendy

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Octahydro‐1,2,3:4,5,6‐dimethenopentalene‐2‐carbonitrile, the First Derivative of a Yet‐Unknown (CH) 10 Hydrocarbon

Author(s) -

Christl Manfred,

Türk Michael,

Peters EvaMaria,

Peters Karl,

von Schnering Hans Georg

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199416391

Subject(s) - hydrocarbon , derivative (finance) , chemistry , medicinal chemistry , combinatorics , mathematics , organic chemistry , economics , financial economics

Two proximate bicyclobutane units are contained in the new hexacycle 3 . Their arrangement facilitates a transannular reaction in the radical addition of thiophenol to give the cage compound 4 . Starting from benzvalene ( 1 ), the route to 3 comprises only five steps: the first ( 1 → 2 ) is a Pauson‐Khand reaction.

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