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Octahydro‐1,2,3:4,5,6‐dimethenopentalene‐2‐carbonitrile, the First Derivative of a Yet‐Unknown (CH) 10 Hydrocarbon
Author(s) -
Christl Manfred,
Türk Michael,
Peters EvaMaria,
Peters Karl,
von Schnering Hans Georg
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199416391
Subject(s) - hydrocarbon , derivative (finance) , chemistry , medicinal chemistry , combinatorics , mathematics , organic chemistry , economics , financial economics
Two proximate bicyclobutane units are contained in the new hexacycle 3 . Their arrangement facilitates a transannular reaction in the radical addition of thiophenol to give the cage compound 4 . Starting from benzvalene ( 1 ), the route to 3 comprises only five steps: the first ( 1 → 2 ) is a Pauson‐Khand reaction.