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61,61‐Bis(trimethylsilylbutadiynyl)‐1,2‐dihydro‐1,2‐methanofullerene[60]: Crystal Structure at 100 K and Electrochemical Conversion to a Conducting Polymer
Author(s) -
Anderson Harry L.,
Boudon Corinne,
Diederich François,
Gisselbrecht JeanPaul,
Gross Maurice,
Seiler Paul
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199416281
Subject(s) - electrochemistry , ring (chemistry) , crystal structure , crystal (programming language) , crystallography , materials science , polymer , polymer chemistry , chemistry , electrode , organic chemistry , composite material , computer science , programming language
The presence of a transannular bond at a methano‐bridged 6–6 ring junction in C 60 was confirmed conclusively with an accurate crystal structure of the title compound 1 , thus putting an end to a heated debate. The length of the 6–6 bond is 1.574(3) Å.