61,61‐Bis(trimethylsilylbutadiynyl)‐1,2‐dihydro‐1,2‐methanofullerene[60]: Crystal Structure at 100 K and Electrochemical Conversion to a Conducting Polymer | Zendy

Anderson Harry L. | Zendy; Boudon Corinne | Zendy; Diederich François | Zendy; Gisselbrecht JeanPaul | Zendy; Gross Maurice | Zendy; Seiler Paul | Zendy

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61,61‐Bis(trimethylsilylbutadiynyl)‐1,2‐dihydro‐1,2‐methanofullerene[60]: Crystal Structure at 100 K and Electrochemical Conversion to a Conducting Polymer

Author(s) -

Anderson Harry L.,

Boudon Corinne,

Diederich François,

Gisselbrecht JeanPaul,

Gross Maurice,

Seiler Paul

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199416281

Subject(s) - electrochemistry , ring (chemistry) , crystal structure , crystal (programming language) , crystallography , materials science , polymer , polymer chemistry , chemistry , electrode , organic chemistry , composite material , computer science , programming language

The presence of a transannular bond at a methano‐bridged 6–6 ring junction in C 60 was confirmed conclusively with an accurate crystal structure of the title compound 1 , thus putting an end to a heated debate. The length of the 6–6 bond is 1.574(3) Å.

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