Premium
Stereoselective Reactions of Sulfinylated Benzyl Radicals: Effects of Solvents and Lewis Acids
Author(s) -
Renaud Philippe,
Bourquard Thierry,
Gerster Michèle,
Moufid Nadira
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199416011
Subject(s) - radical , chemistry , lewis acids and bases , protonation , medicinal chemistry , stereoselectivity , photochemistry , organic chemistry , catalysis , ion
The opposite relative configuration to that observed in the deuteration of de‐protonated sulfoxides of type 2 results from the radical deuteration of sulfinylated benzyl radicals of type 1 in the presence of bulky Lewis acids (methylaluminum diphenoxide).