Preparation and Preliminary Characterization of a Covalently Pillared Zirconium Phosphate‐ Diphosphonate with Interlayer Microporosity | Zendy

Alberti Giulio | Zendy; Marmottini Fabio | Zendy; MurciaMascarós Sonia | Zendy; Vivani Riccardo | Zendy

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Preparation and Preliminary Characterization of a Covalently Pillared Zirconium Phosphate‐ Diphosphonate with Interlayer Microporosity

Author(s) -

Alberti Giulio,

Marmottini Fabio,

MurciaMascarós Sonia,

Vivani Riccardo

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199415941

Subject(s) - covalent bond , zirconium phosphate , zirconium , molecular sieve , phosphate , characterization (materials science) , materials science , catalysis , chemical engineering , inorganic chemistry , chemistry , nanotechnology , organic chemistry , engineering

The computer‐generated structural model on the right clearly shows the interlayer microporosity ( V microp . = 0.12cm 3 g −1 ) of the covalently pillared γ‐zirconium phosphate ‐diphosphonate. Thus, this type of compound could be of interest as a molecular sieve or for shape‐selective catalysis. The pillaring was achieved by a simple topotactic reaction.

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