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Trigonal Symmetry as a Host Design Element: Novel Conformation of Dodecakis(3,5‐dimethyl‐phenylthio)coronene in its 1,4‐Dioxane Clathrate
Author(s) -
Downing Gary A.,
Frampton Christopher S.,
MacNicol David D.,
Mallinson Paul R.
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199415871
Subject(s) - coronene , clathrate hydrate , molecule , chemistry , adduct , crystallography , trigonal crystal system , host (biology) , crystal structure , stereochemistry , hydrate , organic chemistry , ecology , biology
The first versatile coronene‐based host is the dodecathioether 1 . The structure of the highly crystalline 1,4‐dioxane adduct of 1 was elucidated; it revealed that the host molecule has the novel C 3 ‐symmetric aabbaabbaabb conformation.
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