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New Ionic, Isoelectronic Analogues of CO 2 and CS 2
Author(s) -
Klapötke Thomas M.
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199415751
Subject(s) - ion , quantum chemical , ionic bonding , crystallography , ionic crystal , chemistry , crystal structure , inorganic chemistry , computational chemistry , atomic physics , physics , molecule , organic chemistry
The linear arrangement of the atoms in CO 2 also occurs, in most cases, in its anionic analogues NBN 3− and CBN 4− , as well as in the ions SNS + , PCS 3− , and PBP 3− that are analogous to CS 2 . Many of the findings and structures predicted by quantum chemical calculations have since been confirmed by crystal structure analyses. This should encourage the synthesis of additional isoelectronic analogues.