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Synthesis and Structure of the First Titanium( IV ) α‐Amino Acid Complexes
Author(s) -
Klapötke Thomas M.,
Köpf Hartmut,
TornieporthOetting Inis C.,
White Peter S.
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199415181
Subject(s) - amino acid , titanium , chemistry , stereochemistry , biochemistry , organic chemistry
Cytostatically active titanocene dichloride reacts with α‐amino acids to give titanium( IV ) amino acid complexes of the type [Cp 2 Ti(aa) 2 ] 2+ [Cl − ] 2 (aa = α‐amino acid). The structure of the cation ( 1 ) in the corresponding 2‐methylalanine complex is shown on the right.