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Luminescent Eu 3+ and Tb 3+ Complexes of a Branched Macrocyclic Ligand Incorporating 2,2′‐Bipyridine in the Macrocycle and Phosphinate Esters in the Side Arms
Author(s) -
Sabbatini Nanda,
Guardigli Massimo,
Bolletta Fabrizio,
Manet Ilse,
Ziessel Raymond
Publication year - 1994
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199415011
Subject(s) - luminescence , phosphinate , ligand (biochemistry) , lanthanide , chemistry , metal , bipyridine , 2,2' bipyridine , ion , crystallography , stereochemistry , materials science , crystal structure , organic chemistry , receptor , biochemistry , optoelectronics , fire retardant
Kinetic stability in water , good protection of the metal center, and strong luminescence of the metal ion make lanthanide complexes of the ligand 1 ([M⊂ 1 ] 3+ , M = Eu, Tb) promising as luminescent labels in fluoroimmuno‐assays.