Chlorine Trioxide: Spectroscopic Properties, Molecular Structure, and Photochemical Behavior | Zendy

Grothe Hinrich | Zendy; Willner Helge | Zendy

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Chlorine Trioxide: Spectroscopic Properties, Molecular Structure, and Photochemical Behavior

Author(s) -

Grothe Hinrich,

Willner Helge

Publication year - 1994

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199414821

Subject(s) - matrix isolation , chlorine , chemistry , photochemistry , trioxide , photodissociation , flash vacuum pyrolysis , perchlorate , chlorine atom , flash photolysis , pyrolysis , molecule , polymer chemistry , organic chemistry , medicinal chemistry , ion , sulfur , physics , quantum mechanics , reaction rate constant , kinetics

Though postulated for years, now detected for the first time! The symmetric ClO 3 radical was synthesized by vacuum flash pyrolysis of chlorine perchlorate and trapped by matrix isolation for UV and IR spectroscopic studies. The OClO bond angle is 113.5±2° and the ClO bond length 150.0±1 pm. The photolysis of ClO 3 yields the unsymmetric isomer OClOO.

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